Volume 646
Main Index

Issues 1-2, Pages 1-292 (1 March 2002)

Main group chemistry Page 1 F. Mathey

Main Group Chemistry—1999 ICMGC Award Pages 2-3 Guy Bertrand

Organoaluminum chemistry with low valent aluminum — recent developments Pages 4-14 M. N. Sudheendra Rao, Herbert W. Roesky, G. Anantharaman

Phosphametallocenes: from discovery to applications Pages 15-20 François Mathey

Heteroboranes of the p-block elements Pages 21-38 Kamesh Vyakaranam, John A. Maguire, Narayan S. Hosmane

Some recent advances in the chemistry of silicon and its homologues in low coordination states Pages 39-52 Manfred Weidenbruch

Transformations of organosilanes by Pt(II) complexes with hemilabile P,N-chelating ligands Pages 53-58 Ulrich Schubert, Jürgen Pfeiffer, Frank Stöhr, Dietmar Sturmayr, Susan Thompson

Synthesis of heterocycles by cyclization of unsaturated organolithiums: a review Pages 59-67 Michael J. Mealy, William F. Bailey

The quest for triplet ground state silylenes Pages 68-79 Peter P. Gaspar, Manchao Xiao, Dong Ho Pae, Daniel J. Berger, Tesfamichael Haile, Tongqian Chen, Deqing Lei, William R. Winchester, Ping Jiang

Acyclic and heterocyclic tellurathianitrogen compounds: a review on recent publications Pages 80-93 Alois Haas

Lithium phosphonium azayldiides R3P=NLi. Applications in organic synthesis and coordination chemistry Pages 94-106 Henri Jean Cristau, Marc Taillefer, Nicolas Rahier

Imido analogs of aluminophosphates: syntheses and X-ray structures of {LiAl[OP(NtBu)2(NHtBu)]2}2 and the mono- and di-methylaluminum complexes of the anions [OP(NtBu)x(NHtBu)3−x]x− (x=1, 2) Pages 107-112 Pierre Blais, Tristram Chivers, Gabriele Schatte, Mark Krahn

Metalated 1,3-azaphospholes: synthesis of lithium-1,3-benzazaphospholides and reactivity towards organoelement and organometal halides Pages 113-124 Anushka Surana, Shreeyukta Singh, Raj Kumar Bansal, Normen Peulecke, Anke Spannenberg, Joachim Heinicke

Novel organotin halides. Organometallic substituted stannoles and alkene derivatives with tin---chlorine and tin---bromine bonds—exceptionally small magnitude of coupling constants 1J(119Sn, 13C) Pages 125-133 Bernd Wrackmeyer, Gerald Kehr, Sabine Willbold, Saqib Ali

Tetrakis[lithium-tert-butyl(di-tert-butylfluorosilyl)amide]-dilithium oxide, (tBu2SiF–NLitBu)4Li2O—a Li6O4+-cluster Pages 134-137 Michael Jendras, Uwe Klingebiel, Mathias Noltemeyer

New synthetic approach and structural characterization of the chloroalkylstannanes (Cl---CH2)n SnCl4−n (n=2, 4) and the hydrolysis product [(ClCH2)2Sn(Cl)---O---Sn(Cl)(CH2Cl)2]2 Pages 138-145 Michael Veith, Dominique Agustin, Volker Huch

Chemical applications of topology and group theory. Part 36. Deltahedral and fused deltahedral organometallic gallium and indium clusters Pages 146-152 R. Bruce King

Synthesis of 2H-1,2-oxaphosphorin 2-oxides Pages 153-160 Alexandre M. Polozov, Sheldon E. Cremer

P(MeNMCH2CH2)3N: an effective catalyst for trimethylsilycyanation of aldehydes and ketones Pages 161-166 Zhigang Wang, Brandon Fetterly, John G. Verkade

First siloxane tethered paracyclophane Pages 167-170 Sundarraj Sudhakar, Gene-Hsiang Lee, Yu Wang, Jui-Hung Hsu, Tien-Yau Luh

Bis(trifluoromethane)sulfonimide initiated ring-opening polymerization of octamethylcyclotetrasiloxane Pages 171-178 Jean-Roger Desmurs, Léon Ghosez, José Martins, Thomas Deforth, Gérard Mignani

Regio- and stereoselective addition of sterically hindered silylboranes to terminal alkynes Pages 179-190 José Carlos Araujo Da Silva, Marc Birot, Jean-Paul Pillot, Michel Pétraud

Synthesis and structural characterisation of the 3,5-di-tert-butyl-1,2,4-triphospholyl complexes of monovalent gallium and thallium, [M(η5-P3C2Bu2t)], M=Ga, Tl Pages 191-195 Matthew D. Francis, Peter B. Hitchcock, John F. Nixon, Hansgeorg Schnöckel, Jochen Steiner

1,3-Dipolar cycloaddition of alkynyliodonium salts with a nitrile oxide. Synthesis and reactivity of isoxazolyliodonium salts Pages 196-199 Tsugio Kitamura, Yoichiro Mansei, Yuzo Fujiwara

Octakis[(2,2,6,6-tetramethylpiperidino)methyl]octasilsesquioxane: synthesis and crystal structure analysis of a new aminoorganyl-functionalized octasilsesquioxane Pages 200-203 Ingo Richter, Christian Burschka, Reinhold Tacke

Syntheses, structure, and Berry pseudorotation of ruthenium-, iron-, and cobalt-phosphorane complexes Pages 204-211 Hiroshi Nakazawa, Kazumori Kawamura, Tsuyoshi Ogawa, Katsuhiko Miyoshi

Enantioselective synthesis of phosphinyl peptidomimetics via an asymmetric Michael reaction of phosphinic acids with acrylate derivatives Pages 212-222 Xuewei Liu, X. Eric Hu, Xinrong Tian, Adam Mazur, Frank H. Ebetino

Synthesis and reactivity of P-acetylenic (silylamino)phosphines Pages 223-229 Robert H. Neilson, William R. Kucera

Synthesis of 1,2-bis[(diorgano)phosphino]ethanes via Michaelis–Arbuzov type rearrangements Pages 230-238 Lawrence C. Baldwin, Mark J. Fink

Photo-Arbuzov rearrangements of cyclic phosphite systems Pages 239-246 Margaret S. Landis, Nicholas J. Turro, Worawan Bhanthumnavin, Wesley G. Bentrude

Cp*GaCl2 and Cp*2GaCl (Cp*=η1-C5Me5) as starting materials for novel Group 13 element complexes Pages 247-254 E. Leiner, M. Scheer

A role for free phosphinidenes in the reaction of magnesium and sterically encumbered ArPCl2 in solution at room temperature Pages 255-261 Rhett C. Smith, Shashin Shah, John D. Protasiewicz

Very strong anionic homoaromaticity in (deloc-1,3,4)-1-sila-3,4-diboracyclopentane-1-ides, the importance of the energy of the reference system for homoaromatic stabilization energies Pages 262-270 David Scheschkewitz, Matthias Hofmann, Abofazl Ghaffari, Peter Amseis, Carsten Präsang, Wahid Mesbah, Gertraud Geiseler, Werner Massa, Armin Berndt

Reaction pathways towards 1,1,2,2-tetratbutyldistannanes Pages 271-276 U. Englich, U. Hermann, I. Prass, T. Schollmeier, K. Ruhlandt-Senge, F. Uhlig

The coordination number–photophysical properties relationship of trianthrylphosphorus compounds: doubly locked fluorescence of anthryl groups Pages 277-281 Shigehiro Yamaguchi, Seiji Akiyama, Kohei Tamao

Author index Page 283

Subject index Pages 285-289

Contents of volume Pages 291-292